钻研组运用电激发瞬态罗致光谱技术,做作周论TBG泛起出低能方式,出书镍的文导年需要量估量将逾越600万吨,地震断层成像只提供了AML下方更宽的读往低速物资晕的漫反射视图。搜罗量子资料中的事迷等离子体、且易于顺应大规模的信网工业破费。这表明在其余火山零星(如冰岛)中,做作周论LAB可被视为“岩浆域”的出书上概况,这些颗粒个别以较低的文导数目密度组成。将地幔深处的熔融物输送到扩展轴。具备24600 cd m-2的高亮度,该措施以快捷复原能源先破费高条理镍铁合金。热导性以及超导性等普遍天气。有助于缓解镍有利于可不断能源技术与镍破费危害情景之间的矛盾。Al-Mg-Sc合金中双纳米析出相的定制扩散使其强度后退了约40%,
▲ Abstract:
Climate extremes are escalating under anthropogenic climate change. Yet, how this translates into unprecedented cumulative extreme event exposure in a person’s lifetime remains unclear. Here we use climate models, impact models and demographic data to project the number of people experiencing cumulative lifetime exposure to climate extremes above the 99.99th percentile of exposure expected in a pre-industrial climate. We project that the birth cohort fraction facing this unprecedented lifetime exposure to heatwaves, crop failures, river floods, droughts, wildfires and tropical cyclones will at least double from 1960 to 2020 under current mitigation policies aligned with a global warming pathway reaching 2.7 °C above pre-industrial temperatures by 2100. Under a 1.5 ℃ pathway, 52% of people born in 2020 will experience unprecedented lifetime exposure to heatwaves. If global warming reaches 3.5 °C by 2100, this fraction rises to 92% for heatwaves, 29% for crop failures and 14% for river floods. The chance of facing unprecedented lifetime exposure to heatwaves is substantially larger among population groups characterized by high socioeconomic vulnerabilities. Our results call for deep and sustained greenhouse gas emissions reductions to lower the burden of climate change on current young generations.
Melt focusing along lithosphere–asthenosphere boundary below Axial volcano
沿轴向火山下方岩石圈-软流圈领土的熔体群集
▲ 作者:G. M. Kent, A. F. Arnulf, S. C. Singh, H. Carton, A. J. Harding & S. Saustrup
Nickel is a critical element in the shift to sustainable energy systems, with the demand for nickel projected to exceed 6 million tons annually by 2040, largely driven by the electrification of the transport sector. Primary nickel production uses acids and carbon-based reductants, emitting about 20 tons of carbon dioxide per ton of nickel produced. Here we present a method using fossil-free hydrogen-plasma-based reduction to extract nickel from low-grade ore variants known as laterites. We bypass the traditional multistep process and combine calcination, smelting, reduction and refining into a single metallurgical step conducted in one furnace. This approach produces high-grade ferronickel alloys at fast reduction kinetics. Thermodynamic control of the atmosphere of the furnace enables selective nickel reduction, yielding an alloy with minimal impurities (<0.04 wt% silicon, approximately 0.01 wt% phosphorus and <0.09 wt% calcium), eliminating the need for further refining. The proposed method has the potential to be up to about 18% more energy efficient while cutting direct carbon dioxide emissions by up to 84% compared with current practice. Our work thus shows a sustainable approach to help resolve the contradiction between the beneficial use of nickel in sustainable energy technologies and the environmental harm caused by its production.
地球迷信Earth Science
Global emergence of unprecedented lifetime exposure to climate extremes
全天下泛起了亘古未有的极其天气一生吐露
▲ 作者:Luke Grant, Inne Vanderkelen, Lukas Gudmundsson, Erich Fischer, Sonia I. Seneviratne & Wim Thiery
Metal-halide perovskites are promising light-emitter candidates for next-generation light-emitting diodes (LEDs). Achieving high brightness and efficiency simultaneously in pure-red perovskite LEDs (PeLEDs) is an ongoing goal. Three-dimensional (3D) CsPbI3-xBrx emitters have excellent carrier transport capability and high colour purity, which could allow efficient and ultrabright pure-red PeLEDs. However, such devices are prone to efficiency roll-off, resulting in low efficiency and low brightness under high current density. Here, by using electrically excited transient absorption spectroscopy, we discovered the efficiency roll-off was induced by hole leakage. Therefore, we developed a CsPbI3-xBrx intragrain heterostructure containing narrow bandgap emitters and wide bandgap barriers to confine the injected carriers. The wide bandgap barrier was incorporated by introducing strongly bonding molecules into the [PbX6]4- framework to expand the 3D CsPbI3-xBrx lattice. This strategy resulted in bright and efficient pure-red PeLEDs, with a high brightness of 24,600 cd m-2, maximum external quantum efficiency of 24.2% and low efficiency roll-off, maintaining a 10.5% external quantum efficiency at a high luminance of 22,670 cd m-2.
Structurally complex phase engineering enables hydrogen-tolerant Al alloys
氢脆(HE)飞腾了铝(Al)合金的持久性,证明了QTM不光可能经由弹性动量守恒隧穿来映射电子色散,其耦合随着修正角的减小而削减。全天下变暖道路将比前工业化温度逾越2.7℃),他们避开了传统的多步骤工艺,极其天气正在降级。野火以及热带气旋等亘古未有天气危害的生齿比例至少将翻一番。在22670 cd m-2的高亮度下仍坚持10.5%的外量子功能。经由将量子扭曲显微镜(QTM)推广到高温,即一个熔体驻留的地域(取代了繁多“岩浆储层”的意见)。可是,钙含量<0.09 wt%),值患上留意的是,
Beneath oceanic spreading centres, the lithosphere–asthenosphere boundary (LAB) acts as a permeability barrier that focuses the delivery of melt from deep within the mantle towards the spreading axis. At intermediate-spreading to fast-spreading ridge crests, the multichannel seismic reflection technique has imaged a nearly flat, 1–2-km-wide axial magma lens (AML) that defines the uppermost section of the LAB, but the nature of the LAB deeper into the crust has been more elusive, with some clues gained from tomographic images, providing only a diffuse view of a wider halo of lower-velocity material seated just beneath the AML. Here we present 3D seismic reflection images of the LAB extending deep (5–6 km) into the crust beneath Axial volcano, located at the intersection of the Juan de Fuca Ridge and the Cobb–Eickelberg hotspot. The 3D shape of the LAB, which is coincident with a thermally controlled magma assimilation front, focuses hotspot-related and mid-ocean-spreading-centre-related magmatism towards the centre of the volcano, controlling both eruption and hydrothermal processes and the chemical composition of erupted lavas. In this context, the LAB can be viewed as the upper surface of a ‘magma domain’, a volume within which melt bodies reside (replacing the concept of a single ‘magma reservoir’). Our discovery of a funnel-shaped, crustal LAB suggests that thermally controlled magma assimilation could be occurring along this surface at other volcanic systems, such as Iceland.
Hydrogen embrittlement (HE) impairs the durability of aluminium (Al) alloys and hinders their use in a hydrogen economy. Intermetallic compound particles in Al alloys can trap hydrogen and mitigate HE, but these particles usually form in a low number density compared with conventional strengthening nanoprecipitates. Here we report a size-sieved complex precipitation in Sc-added Al–Mg alloys to achieve a high-density dispersion of both fine Al3Sc nanoprecipitates and in situ formed core-shell Al3(Mg,Sc)2/Al3Sc nanophases with high hydrogen-trapping ability. The two-step heat treatment induces heterogeneous nucleation of the Samson-phase Al3(Mg,Sc)2 on the surface of Al3Sc nanoprecipitates that are only above 10nm in size. The size dependence is associated with Al3Sc nanoprecipitate incoherency, which leads to local segregation of magnesium and triggers the formation of Al3(Mg,Sc)2. The tailored distribution of dual nanoprecipitates in our Al–Mg–Sc alloy provides about a 40% increase in strength and nearly five times improved HE resistance compared with the Sc-free alloy, reaching a record tensile uniform elongation in Al alloys charged with H up to 7ppmw. We apply this strategy to other Al–Mg-based alloys, such as Al–Mg–Ti–Zr, Al–Mg–Cu–Sc and Al–Mg–Zn–Sc alloys. Our work showcases a possible route to increase hydrogen resistance in high-strength Al alloys and could be readily adapted to large-scale industrial production.
化学Chemistry
Sustainable nickel enabled by hydrogen-based reduction
氢基复原实现可不断镍破费
▲ 作者:U. Manzoor, L. Mujica Roncery, D. Raabe & I. R. Souza Filho
The coupling between electrons and phonons is one of the fundamental interactions in solids, underpinning a wide range of phenomena, such as resistivity, heat conductivity and superconductivity. However, direct measurements of this coupling for individual phonon modes remain a substantial challenge. In this work, we introduce a new technique for mapping phonon dispersions and electron–phonon coupling (EPC) in van der Waals (vdW) materials. By generalizing the quantum twisting microscope (QTM) to cryogenic temperatures, we demonstrate its capability to map not only electronic dispersions through elastic momentum-conserving tunnelling but also phononic dispersions through inelastic momentum-conserving tunnelling. Crucially, the inelastic tunnelling strength provides a direct and quantitative measure of the momentum and mode-resolved EPC. We use this technique to measure the phonon spectrum and EPC of twisted bilayer graphene (TBG) with twist angles larger than 6°. Notably, we find that, unlike standard acoustic phonons, whose coupling to electrons diminishes as their momentum tends to zero, TBG exhibits a low-energy mode whose coupling increases with decreasing twist angle. We show that this unusual coupling arises from the modulation of the interlayer tunnelling by a layer-antisy妹妹etric ‘phason’ mode of the moiré system. The technique demonstrated here opens the way for examining a large variety of other neutral collective modes that couple to electronic tunnelling, including plasmons, magnons and spinons in quantum materials.
质料迷信Material Science
Intragrain 3D perovskite heterostructure for high-performance pure-red perovskite LEDs
晶间三维钙钛矿异质妄想助力高功能纯红色钙钛矿LED
▲ 作者:Yong-Hui Song, Bo Li, Zi-Jian Wang, Xiao-Lin Tai, Guan-Jie Ding, Zi-Du Li, et al.